Synthesis and Characterization of Ir-(κ2-NSi) Species Active toward the Solventless Hydrolysis of HSiMe(OSiMe3)2.
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DOI: 10.1021/acs.inorgchem.2c01973
Abstract: The reaction of [IrH(Cl)(κ2-NSitBu2)(coe)] (1) with 1 equiv of PCy3 (or PHtBu2) gives the species [IrH(Cl)(κ2-NSitBu2)(L)] (L = PCy3, 2a; PHtBu2, 2b), which reacts with 1 equiv of AgOTf to afford [IrH(OTf)(κ2-NSitBu2)(L)] (L = PCy3,… read more here.
Keywords: hydrolysis hsime; hsime osime3; h2o; phtbu2 ... See more keywords