Selective Hydrolysis of Primary and Secondary Amides Enabled by Visible Light.
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DOI: 10.1021/acs.orglett.3c00354
Abstract: Amide hydrolysis is a fundamentally important transformation in organic chemistry. Developing hydrolysis procedures under mild conditions with a broad substrate scope is desirable. Herein, by leveraging a photoresponsive auxiliary o-nitroanilide, we established a mild two-step… read more here.
Keywords: secondary amides; hydrolysis primary; selective hydrolysis; visible light ... See more keywords