Hydrolytically Stable and Thermo-Mechanically Tunable Poly(Urethane) Thermoset Networks that Selectively Degrade and Generate Reusable Molecules
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DOI: 10.1021/acsami.2c00485
Abstract: Cross-linked polymeric networks that possess tunable properties and degrade on-demand have broad applications in today’s society. Herein, we report on silyl-containing poly(urethane) (silyl-PU) thermoset networks, which are highly cross-linked stimuli-responsive materials with hydrolytic stability at… read more here.
Keywords: poly urethane; reusable molecules; thermoset networks; hydrolytically stable ... See more keywords
Preparation and Properties of a Hydrolytically Stable Cyclooctyne-Containing Polymer
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DOI: 10.1055/s-0037-1610636
Abstract: A poly[(phenylene vinylene)-co-dibenzocyclooctyne] polymer prepared by Wittig polymerization chemistry between dibenzocyclooctyne bisaldehyde [DIBO-(CHO)2] and bis(triethyleneglycol)phenylbis(tributylphosphonium) dibromide is reported. The resulting polymer exhibits moderate molecular weight (Mn: 10.5 kDa, Mw: 21.3 kDa, Ð: 2.02) and is… read more here.
Keywords: cyclooctyne containing; stable cyclooctyne; polymer; hydrolytically stable ... See more keywords