A Hydrometalation Initiation Mechanism via a Discrete Cobalt-Hydride for a Rapid and Controlled Radical Polymerization.
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DOI: 10.1021/jacs.2c04655
Abstract: Cobalt-mediated radical polymerization (CMRP) is a versatile technique for controlling the polymerization of vinyl monomers via reversible termination using CoII complexes as persistent radical deactivators. Here, we report a facile approach for the in situ… read more here.
Keywords: radical polymerization; cobalt; induction period; hydrometalation ... See more keywords