Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere.
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DOI: 10.1021/jacs.1c06911
Abstract: Enzymes exert control over the reactivity of metal centers with precise tuning of the secondary coordination sphere of active sites. One particularly elegant illustration of this principle is in the controlled delivery of proton and… read more here.
Keywords: coordination sphere; direct aerobic; secondary coordination; hydroperoxo intermediate ... See more keywords