Quest for Green-Solvent Design: From Hydrophilic to Hydrophobic (Deep) Eutectic Solvents.
Sign Up to like & getrecommendations! Published in 2019 at "ChemSusChem"
DOI: 10.1002/cssc.201900147
Abstract: Deep eutectic solvents (DESs) consist of a mixture of two or more solid components, which gives rise to a lower melting point compared to the starting materials. Until recently only hydrophilic DESs were available, and… read more here.
Keywords: dess; quest green; deep eutectic; eutectic solvents ... See more keywords
Preparation of new hydrophobic deep eutectic solvents and their application in dispersive liquid–liquid microextraction of Sudan dyes from food samples
Sign Up to like & getrecommendations! Published in 2021 at "Analytical and Bioanalytical Chemistry"
DOI: 10.1007/s00216-021-03337-0
Abstract: In this work, a new generation of hydrophobic deep eutectic solvents (DESs) was prepared using eugenol (as hydrogen bond donor) and benzyltriethylammonium bromide, benzyltributylammonium bromide, benzyltriethylammonium chloride and benzyltributylammonium chloride (as hydrogen bond acceptor) in… read more here.
Keywords: liquid; sudan dyes; dispersive liquid; deep eutectic ... See more keywords
PC-SAFT modeling of CO2 solubilities in hydrophobic deep eutectic solvents
Sign Up to like & getrecommendations! Published in 2017 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2017.03.028
Abstract: Abstract The PC-SAFT ‘pseudo-pure’ approach was used for the modeling of CO2 solubilities in various hydrophobic deep eutectic solvents (DESs) for the first time. Only liquid density data were used to obtain the segment number,… read more here.
Keywords: co2 solubilities; deep eutectic; modeling co2; eutectic solvents ... See more keywords
Thermodynamic properties of hydrophobic deep eutectic solvents and solubility of water and HMF in them: Measurements and PC-SAFT modeling
Sign Up to like & getrecommendations! Published in 2019 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2019.02.010
Abstract: Abstract Recently, hydrophobic deep eutectic solvents (DESs) were proposed as interesting solvents for biorefinery processes, such as the production of 5-hydroxymethylfurfural (HMF) from glucose in an aqueous environment. Physicochemical property data of hydrophobic DES + water/HMF systems… read more here.
Keywords: water; solubility; hydrophobic deep; water hmf ... See more keywords
Menthol-based hydrophobic deep eutectic solvents: Towards greener and efficient extraction of phytocannabinoids
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Cleaner Production"
DOI: 10.1016/j.jclepro.2018.05.080
Abstract: Abstract As the demand for medical cannabis preparations increases, so does the use of the common organic solvents that are used in the extraction and quantification of phytocannabinoids. Since common organic solvents are typically hazardous… read more here.
Keywords: extraction; greener efficient; extraction phytocannabinoids; deep eutectic ... See more keywords
Dispersive liquid–liquid microextraction based on hydrophobic deep eutectic solvents: Application for tetracyclines monitoring in milk
Sign Up to like & getrecommendations! Published in 2020 at "Microchemical Journal"
DOI: 10.1016/j.microc.2020.105269
Abstract: Abstract In this study, eleven hydrophobic deep eutectic solvents (hDESs) based on some naturally occurring fatty acids, alcohols, and choline chloride were synthesized and evaluated as green extractants in the dispersive liquid–liquid microextraction (DLLME) of… read more here.
Keywords: milk; liquid; dispersive liquid; deep eutectic ... See more keywords
Removal of chlorophenols from aqueous media with hydrophobic deep eutectic solvents: Experimental study and COSMO RS evaluation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.113180
Abstract: Abstract Chlorophenols have been strongly linked with health and environmental risks which includes genotoxicity, mutagenicity, carcinogenicity and histopathological alterations. These hazards are further intensified due to the prevalent usage and disposal. Hence, regulatory bodies have… read more here.
Keywords: extraction; hdess; deep eutectic; eutectic solvents ... See more keywords
Microextraction of sulfonamides from milk samples based on hydrophobic deep eutectic solvent formation by pH adjusting
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2021.116827
Abstract: Abstract A novel approach for liquid-liquid microextraction via formation of hydrophobic deep eutectic solvent by pH adjusting was suggested. This study demonstrated for the first time that an alkaline aqueous solution of terpenoid and medium-chain… read more here.
Keywords: formation; deep eutectic; milk samples; hydrophobic deep ... See more keywords
Hydrophobic Deep Eutectic Solvent and Glycolipid Biosurfactant as Green Asphaltene Inhibitors: Experimental and Theoretical Studies
Sign Up to like & getrecommendations! Published in 2021 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.0c03922
Abstract: Precipitation of asphaltenes in porous media undesirably influences oil recovery due to pore clogging and subsequent wettability alteration. This study reports, primarily, the potential application... read more here.
Keywords: deep eutectic; biosurfactant green; hydrophobic deep; eutectic solvent ... See more keywords
110th Anniversary: Distribution Coefficients of Furfural and 5-Hydroxymethylfurfural in Hydrophobic Deep Eutectic Solvent + Water Systems: Experiments and Perturbed-Chain Statistical Associating Fluid Theory Predictions
Sign Up to like & getrecommendations! Published in 2019 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.8b06234
Abstract: Furfural (FF) and 5-hydroxymethylfurfural (HMF) are intermediates for many products, such as monomers for bioplastics, and can be obtained from various renewable resources. The isolation of these sugar-derived molecules from aqueous solutions is one of… read more here.
Keywords: water systems; distribution coefficients; deep eutectic; hydrophobic deep ... See more keywords
The Curious Case of Hydrophobic Deep Eutectic Solvents: A Story on the Discovery, Design, and Applications
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c00559
Abstract: Hydrophobic deep eutectic solvents (DESs) are a new generation of water immiscible solvents that have been presented in the literature for the first time in 2015. These solvents have been used for ... read more here.
Keywords: solvents story; deep eutectic; curious case; eutectic solvents ... See more keywords