Palladacycle promoted asymmetric hydrophosphination of α,β-unsaturated sulfonyl fluorides
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.120912
Abstract: Abstract The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the… read more here.
Keywords: unsaturated sulfonyl; hydrophosphination; palladacycle promoted; asymmetric hydrophosphination ... See more keywords
Manganese(I)-Catalyzed Asymmetric Hydrophosphination of α,β-Unsaturated Carbonyl Derivatives
Sign Up to like & getrecommendations! Published in 2023 at "Organic Letters"
DOI: 10.1021/acs.orglett.2c04256
Abstract: Here we report catalytic asymmetric hydrophosphination of α,β-unsaturated carbonyl derivatives using a chiral Mn(I) complex as a catalyst. Through H–P bond activation, various phosphine-containing chiral products can be accessed via hydrophosphination of various ketone-, ester-,… read more here.
Keywords: manganese catalyzed; unsaturated carbonyl; asymmetric hydrophosphination; hydrophosphination ... See more keywords