Lanthanum-Catalyzed Double Hydrophosphinylation of Nitriles
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DOI: 10.1021/acs.organomet.6b00919
Abstract: A new lanthanum-based catalyst was shown to be effective for the double hydrophosphinylation of unactivated nitriles under very mild conditions. Surprisingly, the lanthanum catalyst gave two regioisomeric products depending on the nature of the starting… read more here.
Keywords: addition; catalyzed double; lanthanum catalyzed; hydrophosphinylation ... See more keywords
Ni-catalyzed asymmetric hydrophosphinylation of conjugated enynes and mechanistic studies
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DOI: 10.1039/d2sc00091a
Abstract: The catalytic asymmetric synthesis of P-stereogenic phosphines is an efficient strategy to access structurally diverse chiral phosphines that could serve as organocatalysts and ligands to transition metals and motifs of antiviral drugs. Herein, we describe… read more here.
Keywords: hydrophosphinylation conjugated; could serve; catalyzed asymmetric; conjugated enynes ... See more keywords