Preparation of branched molecules by regioselective hydrosilation of tetrakis(ethynyldimethylsilyl)silanes and some of their properties
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.07.015
Abstract: Abstract New types of molecules, tetrasilylsilanes with the arms composed of oligothienylsilylvinyl units, were prepared by the platinum-catalyzed hydrosilation reactions. UV–Vis absorption and fluorescence properties of these molecules have been investigated. Polymer 9 showed good… read more here.
Keywords: regioselective hydrosilation; hydrosilation; hydrosilation tetrakis; branched molecules ... See more keywords
Tandem deoxygenative hydrosilation of carbon dioxide with a cationic scandium hydridoborate and B(C6F5)3.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt04323c
Abstract: A scandium hydridoborate complex supported by the dianionic pentadentate ligand B2Pz4Py is prepared via hydride abstraction from the previously reported scandium hydride complex with tris-pentafluorophenyl borane. Exposure of [(B2Pz4Py)Sc][HB(C6F5)3] to CO2 immediately forms [(B2Pz4Py)Sc][HCOOB(C6F5)3] at… read more here.
Keywords: scandium hydridoborate; tandem deoxygenative; c6f5; hydrosilation ... See more keywords