Syntheses of hydrido selenophenolato iron(II) complexes and their catalytic application in hydrosilylation of aldehydes and ketones
Sign Up to like & getrecommendations! Published in 2018 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2018.06.015
Abstract: Abstract Three novel selenophenolato hydrido iron(II) complexes [cis-(H)(SeAr)Fe(PMe3)4] (4–6) (Ar=C6H5 (4), p-MeOC6H4 (5) and o-MeC6H4 (6)) were prepared through the reaction of Fe(PMe3)4 with selenophenols ArSeH (1–3) via Se–H activation. The iron hydrido complexes 4,… read more here.
Keywords: syntheses hydrido; aldehydes ketones; hydrosilylation aldehydes; iron ... See more keywords
Hydrosilylation of Aldehydes and Ketones Catalyzed by a 2-Iminopyrrolyl Alkyl-Manganese(II) Complex.
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DOI: 10.1021/acs.inorgchem.1c03621
Abstract: A well-defined and very active single-component manganese(II) catalyst system for the hydrosilylation of aldehydes and ketones is presented. First, the reaction of 5-(2,4,6-iPr3C6H2)-2-[N-(2,6-iPr2C6H3)formimino]pyrrolyl potassium (KL) and [MnCl2(Py)2] afforded the binuclear 2-iminopyrrolyl manganese(II) pyridine chloride complex… read more here.
Keywords: aldehydes ketones; spectroscopy; catalyzed iminopyrrolyl; hydrosilylation aldehydes ... See more keywords