Markovnikov Hydrosilylation of Alkenes: How an Oddity Becomes the Goal
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b03104
Abstract: Over the years, hydrosilylation of terminal alkenes has emerged as one of the most prominent applications of homogeneous catalysis. While most of the relevant reports concern β-selective hydrosilylation, yielding linear products which are of industrial… read more here.
Keywords: markovnikov hydrosilylation; becomes goal; hydrosilylation alkenes; oddity becomes ... See more keywords
Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b12938
Abstract: Cobalt(II) complexes capable of catalyzing alkene hydrosilylation in the absence of external activators are rarely known, and their activation mode has remained poorly understood. We present here that cobalt(II) amide complexes, [Co(N(SiMe3)2)2] and its NHC… read more here.
Keywords: cobalt; alkenes tertiary; cobalt amides; hydrosilylation alkenes ... See more keywords
Progress on Iridium-Catalyzed Hydrosilylation of Alkenes and Alkynes
Sign Up to like & getrecommendations! Published in 2020 at "Synthesis"
DOI: 10.1055/s-0040-1707239
Abstract: Hydrosilylation of multiple carbon–carbon bonds is a well-known process for the construction of organosilicon compounds. Nowadays, precious metal catalysts, especially platinum complexes, still occupy dominant positions in such processes. However, one important member of the… read more here.
Keywords: catalyzed hydrosilylation; iridium; hydrosilylation alkenes; iridium catalyzed ... See more keywords
Mechanistic Investigations of Nickamine- catalyzed Hydrosilylation of Alkenes: Nickel Nanoparticles Are the Active Species.
Sign Up to like & getrecommendations! Published in 2020 at "Chimia"
DOI: 10.2533/chimia.2020.444
Abstract: Hydrosilylation is an important chemical process for the synthesis of organosilanes and for the production of silicone polymers. The wide variety of catalysts developed for this reaction generally follow a Chalk-Harrod, or a sigma-bond metathesis… read more here.
Keywords: hydrosilylation alkenes; mechanistic investigations; investigations nickamine; nickamine catalyzed ... See more keywords