Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying π-Bond Migration
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c05424
Abstract: We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying π-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine lig... read more here.
Keywords: alkynes accompanying; hydrosilylation alkynes; catalyzed hydrosilylation; bond migration ... See more keywords
Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00544j
Abstract: A mild, selective and facile synthesis of vinylsilanes via a recyclable platinum nanoparticle catalysed hydrosilylation of alkynes is reported. Various functionalized alkynes are selectively hydrosilylated to furnish functional β-E vinylsilanes in high yields. The catalytic… read more here.
Keywords: hydrosilylation alkynes; catalysed hydrosilylation; vinylsilanes via; nanoparticle catalysed ... See more keywords
Regio- and stereoselective hydrosilylation of alkynes catalyzed by SiO2 supported Pd–Cu bimetallic nanoparticles
Sign Up to like & getrecommendations! Published in 2017 at "Green Chemistry"
DOI: 10.1039/c7gc00818j
Abstract: An efficient, recyclable Pd–Cu bimetallic nanoparticle catalyst has been prepared, which exhibits superior activity and selectivity toward the hydrosilylation of internal and terminal alkynes under mild reaction conditions with a low catalyst loading. Distinct enhancement… read more here.
Keywords: hydrosilylation alkynes; bimetallic nanoparticles; chemistry; regio stereoselective ... See more keywords
Atomically dispersed gold anchored on carbon nitride nanosheets as effective catalyst for regioselective hydrosilylation of alkynes
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry A"
DOI: 10.1039/d1ta05528c
Abstract: The atomically dispersed Au catalysts realize hydrosilylation of alkynes with high activity, selectivity and stability. read more here.
Keywords: hydrosilylation alkynes; atomically dispersed; anchored carbon; dispersed gold ... See more keywords
Effect of liquid confinement on regioselectivity in the hydrosilylation of alkynes with cationic Rh(I) N-heterocyclic carbene catalysts.
Sign Up to like & getrecommendations! Published in 2023 at "Faraday discussions"
DOI: 10.1039/d2fd00152g
Abstract: Polymeric mesoporous monoliths were prepared via ring-opening metathesis polymerization (ROMP) from norbornene (NBE), 1,4,4a,5,8,8a-hexahydro-1,4,5,8-exo,endo-dimethanonaphthalene (DMN-H6), tris(norborn-2-enylmethylenoxy)methylsilane and the 1st-generation Grubbs catalyst [RuCl2(PCy3)2(CHC6H5)] in the presence of 2-propanol and toluene and surface grafted with 1-(2-((norborn-5-ene-2-carbonyl)oxy)ethyl)-3-ethyl-1H-imidazol-3-ium tetrafluoroborate.… read more here.
Keywords: catalyst; regioselectivity; liquid confinement; hydrosilylation alkynes ... See more keywords