Multifunctional Catalytic Surface Design for Concerted Acceleration of One-Pot Hydrosilylation-CO2 Cycloaddition.
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DOI: 10.1021/acs.orglett.9b03602
Abstract: Silica-supported Rh-ammonium iodide catalyst showed high performance for hydrosilylation-CO2 cycloaddition reaction sequences. The catalyst was prepared by surface grafting of Rh and the silane-coupling reaction of the ammonium iodide moiety. The acceleration of each catalytic… read more here.
Keywords: co2 cycloaddition; hydrosilylation co2; reaction;