Synthesis of bis(2-pyridylthio)methyl zinc hydride and catalytic hydrosilylation and hydroboration of CO2.
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DOI: 10.1039/d1cc06963b
Abstract: The reactions of bis(2-pyridylthio)methane with Me2Zn and Zn[N(SiMe3)2]2 afford [Bptm]ZnMe and [Bptm]ZnN(SiMe3)2, thereby providing access to a variety of other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves as a catalyst for the… read more here.
Keywords: bis pyridylthio; hydrosilylation hydroboration; bptm; zinc hydride ... See more keywords