Copper-Catalyzed Highly Selective Hydrosilylation of Silyl or Boryl Alkene: A Method for Preparing Chiral Geminated Disilyl and Borylsilyl Reagents.
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DOI: 10.1021/acs.orglett.2c00858
Abstract: The copper-catalyzed highly selective hydrosilylation of silyl or boryl alkene has been developed. This chemistry could afford a practical method for preparing chiral geminated disilyl and borylsilyl reagents, which are useful organosilanes and versatile synthons… read more here.
Keywords: chemistry; selective hydrosilylation; hydrosilylation silyl; copper catalyzed ... See more keywords
Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates
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DOI: 10.1055/s-0036-1591508
Abstract: An iron catalyst is shown for the first time to promote transfer hydrosilylation with silyl formates and is utilized for the silylation of alcohols. Attractive features of this protocol include the use of an earth-abundant… read more here.
Keywords: transfer hydrosilylation; silyl formates; silylation alcohols; hydrosilylation silyl ... See more keywords