Enantioselective hydrosilylation of unsaturated carbon–heteroatom bonds (CN, CO) catalyzed by [Ru–S] complexes: a theoretical study
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DOI: 10.1039/c9ra10760f
Abstract: A detailed theoretical study on the mechanism of enanthioselective hydrosilylation of imines and ketones catalyzed by the ruthenium(II) thiolate catalyst [Ru–S] ([L*-Ru(SDmp)]+[BAr4F]−) with a chiral monodentate phosphine ligand is carried out in this work. We… read more here.
Keywords: enantioselective hydrosilylation; carbon; theoretical study; hydrosilylation unsaturated ... See more keywords