Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing.
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DOI: 10.1021/jacs.8b01185
Abstract: Two new base-free hydrosilylene complexes of iron were synthesized using the novel starting material Cp*( iPr2MeP)FeMes. These Cp*( iPr2MeP)Fe(H)SiHR (R = DMP, Trip) complexes are in equilibrium with the corresponding iron silyl complexes, Cp*( iPr2MeP)FeSiH2R,… read more here.
Keywords: base free; hydrosilylene complexes; free iron;