Copper-Catalyzed Transfer Markovnikov Hydrothiolation of Alkenes.
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DOI: 10.1021/acs.orglett.5c02764
Abstract: A copper(II) triflate catalyzed transfer hydromethylthiolation of alkenes has been developed using commercially available and easy-to-handle β-methylthioketone as the methanethiol donor under air. This method exclusively provides Markovnikov products. The reaction demonstrates a broad substrate… read more here.
Keywords: markovnikov hydrothiolation; transfer; hydrothiolation alkenes; copper catalyzed ... See more keywords
Visible light initiated hydrothiolation of alkenes and alkynes over ZnIn2S4
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DOI: 10.1039/c9gc00328b
Abstract: A green, sustainable and cost-effective strategy for the synthesis of thiolated products. read more here.
Keywords: initiated hydrothiolation; light initiated; visible light; alkenes alkynes ... See more keywords
Bifunctional iron-mediated multicomponent Markovnikov-selective radical hydrothiolation of alkenes
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DOI: 10.1039/d5qo00308c
Abstract: A bifunctional iron-mediated multicomponent reaction for Markovnikov-selective hydrothiolation of alkenes has been established. The reaction involves an iron-mediated hydrogen atom transfer and a single electron transfer process. read more here.
Keywords: mediated multicomponent; bifunctional iron; markovnikov selective; hydrothiolation alkenes ... See more keywords