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Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c00939
Abstract: In this article, we advance Rh-catalyzed hydrothiolation through the divergent reactivity of cyclopropenes. Cyclopropenes undergo hydrothiolation to provide cyclopropyl sulfides or allylic sulfides. The choice of bisphosphine ligand dictates whether the pathway involves ring-retention or…
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Keywords:
hydrothiolation diverging;
diverging cyclopropenes;
cyclopropenes ligand;
cyclopropyl ... See more keywords