Three Different Modes of Association between Metal Cations in Heterometallic Uranyl-CoIII and Uranyl-MnII Species
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DOI: 10.1002/ejic.201800873
Abstract: Three heterometallic complexes including uranyl and either Co$^{III}$ or Mn$^{II}$ cations were crystallized under hydrothermal conditions. Complexes [Co(bipy)$_3$]$_2$[UO$_2$(NO$_3$)$_4$]$_2$[(UO$_2$)$_2$(NO$_3$)$_4$(OH)$_2$] (1) and [UO$_2$(NO$_3$)$_2$Co(bipy)$_2$(OH)$_2$]·NO$_3$·H$_2$O (2) (bipy = 2,2ʹ‐bipyridine) were obtained from the same solution. UO$_2{^{2+}}$ and Co$^{3+}$ are… read more here.
Keywords: different modes; heterometallic uranyl; hydroxo bridged; metal cations ... See more keywords