One Step Closer to an Ideal Insensitive Energetic Molecule: 3,5-Diamino-6-hydroxy-2-oxide-4-nitropyrimidone and its Derivatives.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c05292
Abstract: Reaching the goal of developing an insensitive high-energy molecule (IHEM) is a major challenge. In this study, 3,5-diamino-6-hydroxy-2-oxide-4-nitropyrimidone (IHEM-1) was synthesized in one step from 2,4,6-triamino-5-nitropyrimidine-1,3-dioxide hydrate (ICM-102 hydrate). The density of compound IHEM-1 is… read more here.
Keywords: diamino hydroxy; molecule; ideal insensitive; oxide nitropyrimidone ... See more keywords
Stabilization of ultrathin (hydroxy)oxide films on transition metal substrates for electrochemical energy conversion
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DOI: 10.1038/nenergy.2017.70
Abstract: Development of electrocatalysts with high stability and activity is a critical challenge. Here, the authors combine simulations with in situ experiments to identify principles underlying simultaneously enhanced stability and activity of ultrathin (hydroxy)oxide films on… read more here.
Keywords: transition metal; films transition; oxide films; ultrathin hydroxy ... See more keywords
N-Hydroxy-N-oxide photoinduced tautomerization and excitation wavelength dependent luminescence of ESIPT-capable zinc(II) complexes with a rationally designed 1-hydroxy-2,4-di(pyridin-2-yl)-1H-imidazole ESIPT-ligand.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01232d
Abstract: The ability of 1-hydroxy-1H-imidazoles to undergo proton transfer processes and to exist in N-hydroxy and N-oxide tautomeric forms can be used in coordination chemistry for the design of ESIPT-capable complexes. A series of ESIPT-capable zinc(II)… read more here.
Keywords: excitation wavelength; hydroxy oxide; esipt; ligand ... See more keywords