Articles with "hydroxyethylphosphonate" as a keyword



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Fenton-Derived OH Radicals Enable the MPnS Enzyme to Convert 2-Hydroxyethylphosphonate to Methylphosphonate: Insights from Ab Initio QM/MM MD Simulations.

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Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b02659

Abstract: The mechanism for dioxygen activation represents one of the core issues in metalloenzymes. In most cases, the activation of the O2 molecule requires additional electrons from an external reducant. However, nonheme hydroxyethylphosphonate dioxygenase (HEPD) and… read more here.

Keywords: hydroxyethylphosphonate; methylphosphonate; mpns enzyme; activation ... See more keywords