Cyclopentanone Derivatives from 5-Hydroxymethylfurfural via 1-Hydroxyhexane-2,5-dione as Intermediate.
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DOI: 10.1002/cssc.201702100
Abstract: An efficient strategy for the conversion of biomass derived 5-hydroxymethylfurfural (HMF) into 2-hydroxy-3-methylcyclopent-2-enone (MCP) by an intramolecular aldol condensation of 1-hydroxyhexane-2,5-dione (HHD) has been developed. Further transformations of MCP towards the diol, enol acetate, levulinic… read more here.
Keywords: cyclopentanone derivatives; hydroxyhexane; hydroxyhexane dione; derivatives hydroxymethylfurfural ... See more keywords