Role of surface hydroxyl species in copper catalyzed hydrogenation of ketones
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01652
Abstract: A comprehensive, coverage-dependent mean-field microkinetic model is developed for the hydrogenation of carbonyl compounds on Cu(111). In the model, hydrogenation by surface hydrogen, surface hydroxyl species, and adsorbed water molecules is considered, including a reaction… read more here.
Keywords: role surface; hydrogenation; surface; surface hydroxyl ... See more keywords
Steering CO2 electroreduction pathway toward ethanol via surface-bounded hydroxyl species-induced noncovalent interaction.
Sign Up to like & getrecommendations! Published in 2023 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2218987120
Abstract: Selective electroreduction of carbon dioxide (CO2RR) into ethanol at an industrially relevant current density is highly desired. However, it is challenging because the competing ethylene production pathway is generally more thermodynamically favored. Herein, we achieve… read more here.
Keywords: hydroxyl species; surface bounded; noncovalent interaction; electroreduction ... See more keywords