Nondirected, Cu-Catalyzed sp3 C-H Aminations with Hydroxylamine-Based Amination Reagents: Catalytic and Mechanistic Studies.
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DOI: 10.1021/acs.organomet.7b00003
Abstract: This work demonstrates the use of hydroxylamine-based amination reagents RSO2NH-OAc for the nondirected, Cu-catalyzed amination of benzylic C-H bonds. The amination reagents can be prepared on a gram scale, are benchtop stable, and provide benzylic… read more here.
Keywords: amination reagents; hydroxylamine based; based amination; mechanistic studies ... See more keywords