Photoredox-Catalyzed Synthesis of β-Amino Alcohols: Hydroxymethylation of Imines with α-Silyl Ether as Hydroxymethyl Radical Precursor.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03633
Abstract: Carbon-carbon bond formation is an efficient approach for the synthesis of amino alcohols using two simple starting materials. Herein, we present a novel method for a divergent synthesis of β-amino ethers and β-amino alcohols in… read more here.
Keywords: hydroxymethyl radical; amino alcohols; photoredox catalyzed; synthesis amino ... See more keywords
Laboratory detection of the rotational-tunnelling spectrum of the hydroxymethyl radical, CH2OH
Sign Up to like & getrecommendations! Published in 2017 at "Astronomy and Astrophysics"
DOI: 10.1051/0004-6361/201629508
Abstract: Context. Of the two structural isomers of CH 3 O, methoxy is the only radical whose astronomical detection has been reported through the observation of several rotational lines at 2 and 3 mm wavelengths. Although… read more here.
Keywords: hydroxymethyl radical; detection; detection rotational; spectrum ... See more keywords