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   Articles with "hydroxynitrile lyase" as a keyword



A Single Enzyme in Enantiocomplementary Synthesis of β‐Nitroalcohols: Bidirectional Catalysis by Hydroxynitrile Lyase

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recommendations! Published in 2024 at "ChemBioChem"

DOI: 10.1002/cbic.202400618

Abstract: A single enzyme, Baliospermum montanum hydroxynitrile lyase (BmHNL), without alteration, enabled bidirectional catalysis in enantiocomplementary synthesis of chiral β‐nitroalcohols. BmHNL catalyzed promiscuous Henry (24 examples) and retro‐Henry reaction (22 examples) provided up to >99 % and… read more here.

Keywords: hydroxynitrile lyase; bidirectional catalysis; synthesis; single enzyme ... See more keywords

Baliospermum montanum hydroxynitrile lyase catalyzed synthesis of chiral cyanohydrins in a biphasic solvent

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recommendations! Published in 2018 at "Biocatalysis and agricultural biotechnology"

DOI: 10.1016/j.bcab.2018.08.008

Abstract: Abstract This study presents asymmetric synthesis of cyanohydrins in aqueous–organic biphasic system using crude Baliospermum montanum hydroxynitrile lyase (BmHNL). The effect of various biocatalytic parameters e.g. different organic solvents, ratio of organic solvents, substrate concentration… read more here.

Keywords: montanum hydroxynitrile; hydroxynitrile lyase; chiral cyanohydrins; baliospermum montanum ... See more keywords

Discovery and Structural Analysis to Improve the Enantioselectivity of Hydroxynitrile Lyase from Parafontaria laminata Millipedes for (R)-2-Chloromandelonitrile Synthesis

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recommendations! Published in 2020 at "ACS Omega"

DOI: 10.1021/acsomega.0c03070

Abstract: Hydroxynitrile lyase (HNL) catalyzes the reversible synthesis and degradation of cyanohydrins, which are important synthetic intermediates for fine chemical and pharmaceutical industries. Here, we report the discovery of HNL from Parafontaria laminata (PlamHNL) millipedes, purification… read more here.

Keywords: parafontaria laminata; enantioselectivity; hydroxynitrile lyase; hnl ... See more keywords

Hydroxynitrile lyase defends Arabidopsis against Tetranychus urticae.

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recommendations! Published in 2022 at "Plant physiology"

DOI: 10.1093/plphys/kiac170

Abstract: Plant-pest interactions involve multifaceted processes encompassing a complex crosstalk of pathways, molecules, and regulators aimed at overcoming defenses developed by each interacting organism. Among plant defensive compounds against phytophagous arthropods, cyanide-derived products are toxic molecules… read more here.

Keywords: mutant lines; physiology; tetranychus urticae; hydroxynitrile lyase ... See more keywords