[PtZn2Ge18(Hyp)8] (Hyp = Si(SiMe3)3): A Neutral Polynuclear Chain Compound with Ge9(Hyp)3 Units.
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DOI: 10.1021/acs.inorgchem.8b01757
Abstract: The reaction of [ZnGe18(Hyp)6] (Hyp = Si(SiMe3)3) with Pt(PPh3)4 gives the neutral polynuclear complex of Ge9(Hyp)3 units [HypZn-Ge9(Hyp)3-Pt-Ge9(Hyp)3-ZnHyp], 1. Within 1, the central Pt atom is bound η3 to both Ge9(Hyp)3 units to which further… read more here.
Keywords: hyp hyp; hyp units; ge9 hyp; hyp ... See more keywords
Substitution of Hyp (Hyp = Si(SiMe3)3) at metalloid [Ge9(Hyp)3]- clusters using phosphine stabilized Au(I)Cl.
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DOI: 10.1039/d2dt01665f
Abstract: We present two new intermetalloid cluster compounds [(nBu3P)AuGe9(Hyp)2Au(PnBu3)]2 (1) and [Au(iPr2POC6H4OPiPr2)AuGe9(Hyp)2]2 (2) which are obtained from the reaction of KGe9(Hyp)3 (Hyp = Si(SiMe3)3) with the respective Au(I) phosphine precursors. The products are characterized via X-ray… read more here.
Keywords: substitution hyp; hyp; hyp sime3; hyp hyp ... See more keywords