Articles with "hypophosphorous acid" as a keyword



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Layer-by-Layer Assembly of Hypophosphorous Acid-Modified Chitosan Based Coating for Flame-Retardant Polyester–Cotton Blends

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Published in 2017 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.7b02303

Abstract: Hypophosphorous acid-modified chitosan (PCS), as a novel phosphorus-containing chitosan derivative, was first successfully synthesized and characterized by Fourier transform infrared spectrometry and X-ray photoelectron spectroscopy. Subsequently, thin films of the ecofriendly PCS and branched polyethylenimine… read more here.

Keywords: layer; layer layer; polyester cotton; modified chitosan ... See more keywords

Oxidation of Hypophosphorous Acid by a Ruthenium(VI) Nitrido Complex in Aqueous Acidic Solution. Evidence for a Proton-Coupled N-Atom Transfer Mechanism.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c01627

Abstract: The oxidation of hypophosphorous acid (H3PO2) by a ruthenium(VI) nitrido complex, [(L)RuVI(N)(OH2)]+ (RuVIN; L = N,N'-bis(salicylidene)-o-cyclohexyldiamine dianion), has been studied in aqueous acidic solutions at pH 0-2.50. The reaction has the following stoichiometry: 2[(L)RuVI(N)(OH2)]+ +… read more here.

Keywords: nitrido complex; oxidation; oxidation hypophosphorous; ruthenium nitrido ... See more keywords