Acid Catalysis in the Oxidation of Substrates by Mononuclear Manganese(III)-Aqua Complexes.
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DOI: 10.1021/acs.inorgchem.2c00430
Abstract: Acids are known to enhance the reactivities of metal-oxygen intermediates, such as metal-oxo, -hydroperoxo, -peroxo, and -superoxo complexes, in biomimetic oxidation reactions. Although metal-aqua (and metal-hydroxo) complexes have been shown to be potent oxidants in… read more here.
Keywords: acid catalysis; oxidation; aqua complexes; aqua ... See more keywords