Articles with "iii based" as a keyword



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Luminescent Pr(III)-Based Coordination Polymer: Syntheses, Structures, N2 and CO2 Adsorption Properties

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Published in 2019 at "Journal of Cluster Science"

DOI: 10.1007/s10876-019-01667-9

Abstract: A new Pr(III)-based metal organic framework with formula {[Pr 2 (C 8 H 3 O 6 N)(SO 4 ) 2 ]·5H 2 O} n was hydrothermally synthesized and characterized by techniques of single crystal X-ray… read more here.

Keywords: adsorption; adsorption properties; based coordination; luminescent iii ... See more keywords
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Effective utilization of Fe(III)-based metal organic framework-coated cellulose paper for highly efficient elimination from the liquid phase of paracetamol as a pharmaceutical pollutant

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Published in 2021 at "Environmental Technology and Innovation"

DOI: 10.1016/j.eti.2021.101799

Abstract: Abstract This work aims to evaluate the potential utilization of Fe(III)-based metal organic framework-coated cellulose paper (MIL-100(Fe)@CP) for the elimination of paracetamol (PCM) from water systems. The characterization of MIL-100(Fe)@CP was examined with Fourier transform… read more here.

Keywords: iii based; pcm; utilization iii; based metal ... See more keywords
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Crystal structure and single-molecule magnet behavior of a novel tetranuclear Dy(III)-based cluster

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Published in 2021 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2020.129373

Abstract: Abstract By using a polydentate Schiff base ligand (H3L), in this paper, a new Dy(III)-based cluster, namely [Dy4(HL)4(CH3O)4]·4CH3OH (1), was successfully obtained and further characterized by single-crystal X-ray diffraction. The crystal  structure measurement suggests that… read more here.

Keywords: single molecule; iii based; molecule magnet; structure ... See more keywords
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Selective fluorescent sensing and photodegradation properties of Tb(III)-based MOFs with different bulky backbone ligands

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2018.09.066

Abstract: Abstract Two Tb(III)-based metal–organic frameworks (MOFs) with different bulky ligands, namely [Tb2(L1)0.5(L1)0.5(L1)0.5(L1)0.5(L1)0.5(L1)0.5(DMA)]n (1) and [Tb(L2)0.5(L2)0.5(L2)0.5(DMF)]n (2) (H2L1 = naphthalene-1,4-dicarboxylic acid, H2L2 = anthracene-9,10-dicarboxylic acid, DMA = N,N-dimethylacetamide and DMF = N,N-dimethylformamide), were solvothermally synthesized and structurally characterized by elemental analyses, IR spectra and… read more here.

Keywords: iii based; fluorescent; topology; different bulky ... See more keywords
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La(III)-based MOFs with 5-aminoisophthalic acid for optical detection and degradation of organic molecules in water

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2019.01.045

Abstract: Abstract Two La(III)-based metal–organic frameworks (MOFs) with 5-aminoisophthalic acid (H2L), namely [La(L)1.5(H2O)]n (1) and {[La(L)(Ox)0.5(H2O)2](H2O)}n (2) (H2Ox = oxalic acid), were hydro/solvothermally synthesized and structurally characterized by elemental analyses, IR spectra and X-ray diffraction (XRD) analyses. Single… read more here.

Keywords: iii based; based mofs; mofs aminoisophthalic; aminoisophthalic acid ... See more keywords
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Magnetic refrigeration property and slow magnetic relaxation behavior of five dinuclear Ln(III)-based compounds

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Published in 2021 at "Polyhedron"

DOI: 10.1016/j.poly.2020.114938

Abstract: Abstract In this work, a series of dinuclear Ln(III)-based compounds with the molecular form [Ln2(L)2(dbm)2(H2O)2]·nCH3OH (Ln(III) = Eu (1) , Gd (2), Tb (3), Dy (4) and Ho (5), Hdbm = 1,3-diphenyl-1,3-propanedione and H2L =… read more here.

Keywords: refrigeration property; dinuclear iii; slow magnetic; magnetic refrigeration ... See more keywords
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One-pot synthesis of 2-oxa-7-azaspiro[4.4]nonane-8,9-diones using Mn(III)-based oxidation of 4-acylpyrrolidine-2,3-diones☆

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Published in 2017 at "Tetrahedron Letters"

DOI: 10.1016/j.tetlet.2017.08.002

Abstract: Abstract 2-Oxa-7-azaspiro[4.4]nonane-8,9-diones were newly synthesized in good yields by the Mn(III)-based reaction of a mixture of 1,1-diarylethenes and 4-acylpyrrolidine-2,3-diones. Under the stated reaction conditions, the pyrrolidinedione ring remained intact and became one of the two… read more here.

Keywords: nonane diones; azaspiro; acylpyrrolidine diones; oxa azaspiro ... See more keywords
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Iridium(III)-based chemosensors for the detection of metal ions.

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Published in 2019 at "Methods"

DOI: 10.1016/j.ymeth.2019.02.013

Abstract: In recent years, transition metal complexes with their prominent photophysical properties have emerged as versatile chemosensors to probe different target analytes, including metal ions. By incorporating specific metal ion receptors, various iridium(III) complex-based cation sensors… read more here.

Keywords: iii; iridium iii; metal ions; based chemosensors ... See more keywords
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Theoretical Investigation of Single-Molecule-Magnet Behavior in Mononuclear Dysprosium and Californium Complexes

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Published in 2023 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.2c04013

Abstract: Early-actinide-based (U, Np, and Pu) single-molecule magnets (SMMs) have yet to show magnetic properties similar to those of highly anisotropic lanthanide-based ones. However, there are not many studies exploring the late-actinides (more than half-filled f… read more here.

Keywords: iii complex; single molecule; behavior; iii ... See more keywords
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Photochemically Tuned Magnetic Properties in an Erbium(III)-Based Easy-Plane Single-Molecule Magnet.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.9b01831

Abstract: The magnetic properties of single-molecule magnets can be controlled by external conditions such as light, pressure, and temperature. Among these conditions, photochemical control is the best approach due to the accessibility and rapid conduction of… read more here.

Keywords: single molecule; magnetic properties; bpe; iii based ... See more keywords
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Exploring the photo-toxicity of hypoxic active iridium(III)-based sensitizers in 3D tumor spheroids.

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Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b07723

Abstract: Among all molecules developed for anticancer therapies, photodynamic therapeutic agents have a unique profile. Their maximal activity is specifically triggered in tumors by light and toxicity of even systemically delivered drug is prevented in non-illuminated… read more here.

Keywords: oxygen; toxicity; tumor spheroids; iii based ... See more keywords