Gold(I)···Lanthanide(III) Bonds in Discrete Heterobimetallic Compounds: A Combined Computational and Topological Study
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DOI: 10.1021/acs.inorgchem.2c02717
Abstract: The chemical nature of the ligand-unsupported gold(I)–lanthanide(III) bond in the proposed [LnIII(η5-Cp)2][AuIPh2] (Ln–Au; LnIII = LaIII, EuIII, or LuIII; Cp = cyclopentadienide; Ph = phenyl) models is examined from a theoretical viewpoint. The covalent bond-like… read more here.
Keywords: lanthanide iii; iii bonds; gold lanthanide; bond ... See more keywords
Migratory Insertion of Carbenes into Au(III)–C Bonds
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DOI: 10.1021/jacs.7b11435
Abstract: Migratory insertion of carbon-based species into transition-metal–carbon bonds is a mechanistic manifold of vast significance: it underlies the Fischer–Tropsch process, Mizoroki–Heck reaction, Ziegler–Natta and analogous late-transition-metal-catalyzed olefin polymerizations, and a number of carbonylative methods for… read more here.
Keywords: migratory insertion; carbon; insertion; iii bonds ... See more keywords