Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121843
Abstract: Abstract N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands—trans-[Fe(L-κ3N,C,S)(CO)(PR3)2]PF6 ([1]PF6, R = Me; [ 2 ]PF6, R = OEt) are light-inducible CO releasers under ambient conditions. Optical wavelength ranges corresponding to such a CO release depend on the phosphorous… read more here.
Keywords: phosphorous ligands; pf6; iron iii; iii carbonyl ... See more keywords
CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01407
Abstract: Light-induced CO release from newly synthesized N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands- trans-[Fe(L-κ3 N,C,S)(CO)(PR2R')2]PF6 ([1]PF6, R = Me, R' = Ph; [2]PF6, R = R' = Me; [3]PF6, R = R' = OEt)-were… read more here.
Keywords: pf6; pf6 pf6; carbonyl complexes; iii carbonyl ... See more keywords
Experimental and theoretical studies on gold(III) carbonyl complexes: reductive C,H- and C,C bond formation.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt01315g
Abstract: The reactivity of cationic (C^C)gold(iii) carbonyl complexes was investigated. While the in situ-formed IPrAu(bph)CO+ complex (bph = biphenyl-2,2'-diyl) does not undergo a migratory insertion of CO into the neighboring gold-carbon bond, nucleophiles can attack the… read more here.
Keywords: gold; iii carbonyl; bond; gold iii ... See more keywords