Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization.
Sign Up to like & getrecommendations! Published in 2018 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.7b00444
Abstract: The history of transition metal catalysis is heavily steeped in ligand design, clearly demonstrating the importance of this approach. The intimate relationship between metal and ligand can profoundly affect the outcome of a reaction, often… read more here.
Keywords: iii; electronic steric; iii catalysis; catalysis ... See more keywords
Electro-Oxidative C-C Alkenylation by Rhodium(III) Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b13692
Abstract: Electrochemical C-C activations were accomplished by expedient oxidative rhodium(III) catalysis. Thus, oxidative C-C alkenylations proved viable with the aid of electricity, avoiding the use of toxic and/or expensive transition-metal oxidants. The chelation-assisted C-C functionalizations proceeded… read more here.
Keywords: oxidative alkenylation; rhodium; iii catalysis; electro oxidative ... See more keywords
The interplay of carbophilic activation and Au(I)/Au(III) catalysis: an emerging technique for 1,2-difunctionalization of C-C multiple bonds.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Society reviews"
DOI: 10.1039/d0cs00700e
Abstract: Gold complexes have emerged as the catalysts of choice for various functionalization reactions of C-C multiple bonds due to their inherent carbophilic nature. In a parallel space, efforts to realize less accessible cross-coupling reactivity have… read more here.
Keywords: activation iii; iii catalysis; carbophilic activation; catalysis ... See more keywords
Expanding organofluorine chemical space: the design of chiral fluorinated isosteres enabled by I(i)/I(iii) catalysis
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc02880d
Abstract: Short aliphatic groups are prevalent in bioactive small molecules and play an essential role in regulating physicochemistry and molecular recognition phenomena. Delineating their biological origins and significance have resulted in landmark developments in synthetic organic… read more here.
Keywords: expanding organofluorine; iii catalysis; catalysis; chemical space ... See more keywords
An I(I)/I(III) Catalysis Route to the Heptafluoroisopropyl Group: A Privileged Module in Contemporary Agrochemistry
Sign Up to like & getrecommendations! Published in 2021 at "Synthesis"
DOI: 10.1055/a-1485-4916
Abstract: The heptafluoroisopropyl group is emerging as a privileged chemotype in contemporary agrochemistry and features prominently in the current portfolio of leading insecticides. To reconcile the expansive potential of this module with the synthetic challenges associated… read more here.
Keywords: iii catalysis; contemporary agrochemistry; heptafluoroisopropyl group;