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   Articles with "iii cluster" as a keyword



A channeled 3D structure of a new polyoxometalate-based triiron(III) cluster: Synthesis, crystal structure and electrochemical properties

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recommendations! Published in 2017 at "Polyhedron"

DOI: 10.1016/j.poly.2017.03.052

Abstract: Abstract Tripotassium-tris[(µ3-oxido)triaqua-hexakis(acetato)triiron(III)](octadecatungsto-diphosphato(V))ditriacontahydrate, K3[Fe3O(CH3COO)6(H2O)3]3[P2W18O62]·32H2O (1) is constructed from Wells–Dawson type polyanion [α-P2W18O62]6− and triiron(III) cluster cations [Fe3O(CH3COO)6(H2O)3]+ which are assembled by potassium ions to form a supramolecular structure with nanoscale tunnels running parallel to the c-axis.… read more here.

Keywords: iii cluster; triiron iii; structure;

Bio-mimetic of catecholase and phosphatase activity by a tetra-iron(III) cluster

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recommendations! Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2019.114156

Abstract: Abstract An oxido- and acetato-bridged tetranuclear iron(III) cluster, [Fe4III(µ-O)2(µ-OAc)6(phen)2(H2O)2](NO3)2·(H2O)3 (1), [OAc = acetate; phen = 1,10-phenanthroline] has been prepared in the crystalline phase. X-ray structural analysis of the compound reveals that all the Fe(III) centres in 1 adopt an… read more here.

Keywords: iii cluster; iron; iron iii; tetra iron ... See more keywords

Dual-Color Visual Ratiometric Fluorescence Sensing for H2O and D2O Mixtures Using a Hexanuclear Ln(III) Cluster-Based Metal-Organic Framework.

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recommendations! Published in 2024 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.3c04398

Abstract: High-purity heavy water (D2O) is a strategic material owing to its important application in the fields of nuclear energy and scientific research. D2O always tends to get contaminated by H2O owing to its strong hygroscopicity.… read more here.

Keywords: cluster based; fluorescence; d2o; hexanuclear iii ... See more keywords

Microporous Hexanuclear Ln(III) Cluster-Based Metal-Organic Frameworks: Color Tunability for Barcode Application and Selective Removal of Methylene Blue.

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recommendations! Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.6b02413

Abstract: Two hexanuclear Ln(III) cluster-based metal-organic frameworks (MOFs) (Ln = Tb or Eu) and a series of isomorphic bimetallic Ln(III)-MOFs have been synthesized by changing the ratio of Tb(III) and Eu(III) under solvothermal conditions. The excellent… read more here.

Keywords: iii; cluster based; iii cluster; hexanuclear iii ... See more keywords

3D Printed Voltammetric Sensor Modified with an Fe(III)-Cluster for the Enzyme-Free Determination of Glucose in Sweat

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recommendations! Published in 2022 at "Biosensors"

DOI: 10.3390/bios12121156

Abstract: In this work, a 3D printed sensor modified with a water-stable complex of Fe(III) basic benzoate is presented for the voltammetric detection of glucose (GLU) in acidic epidermal skin conditions. The GLU sensor was produced… read more here.

Keywords: enzyme free; iii cluster; sensor modified; determination ... See more keywords