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1
Published in 2022 at "Chembiochem"
DOI: 10.1002/cbic.202200532
Abstract: We report the synthesis, characterisation, and anti‐osteosarcoma properties of a gallium(III) complex (1) comprising of two 1,10‐phenanthroline ligands and salicylate, a non‐steroidal anti‐inflammatory drug. The gallium(III) complex 1 displays micromolar potency towards bulk osteosarcoma cells…
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Keywords:
iii complex;
cell;
osteosarcoma;
gallium iii ... See more keywords
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Published in 2020 at "BioMetals"
DOI: 10.1007/s10534-020-00235-3
Abstract: A new cyclometalated Au(III) complex highlighting a naphthoquinone-C^N scaffold with formula (NQ-N^C)Au III (SAd)Cl, 1 , in which NQ-N^C: 2-(5-amino-benzo[h]quinolone)-3-(3-methyl-2-butenyl)-1,4-naphthoquinone, HSAd: 1-adamantanethiol, was synthesized and characterized. The interaction of complex 1 with cysteine (CysH) was…
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Keywords:
thioredoxin reductase;
new cyclometalated;
iii complex;
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Published in 2019 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-019-03768-6
Abstract: A metal–organic framework lanthanum(III) complex with formula ([La(pydc)2(H2O)3]·4H2O)n (1), where pydc = pyridine-2,6-dicarboxylic acid, was synthesized through a sonochemical process. Complex 1 was characterized using elemental analysis, atomic absorption spectroscopy, conductivity measurements, Fourier-transform infrared (FT-IR) spectroscopy, thermogravimetric…
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Keywords:
la2o3 nanoparticles;
lanthanum iii;
spectroscopy;
iii complex ... See more keywords
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Published in 2020 at "Science China Chemistry"
DOI: 10.1007/s11426-019-9650-8
Abstract: Trace Ir(III) complex enhanced aggregation-induced electrochemiluminescence (AIECL) of poly-tetraphenylethene (pTPE) in aqueous media was investigated for the first time. The poly-TPE end-capped by Ir(III) complex (Ir@pTPE) and its corresponding model polymer poly-TPE (Ph@pTPE) could be…
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Keywords:
trace iii;
iii;
electrochemiluminescence;
complex enhanced ... See more keywords
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Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1562-9
Abstract: In this work, we have synthesised and structurally characterized a mononuclear cobalt(III) complex, $$[\hbox {Co(2-O-pn)}_{2}]\hbox {Cl}^{.} \hbox {2H}_{2} \hbox {O}$$[Co(2-O-pn)2]Cl.2H2O (1), (2-O-pn = 1,3-diamino-2-propanolate). From the X-ray structure of the cobalt complex, it is revealed…
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Keywords:
cobalt iii;
hbox hbox;
cobalt;
iii complex ... See more keywords
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Published in 2020 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2019.108027
Abstract: Abstract Herein a 23-membered macrocyclic mononuclear Sm(III) complex Sm-2f has been designed and synthesized via the Schiff-base cyclocondensation between extended dialdehyde H2Qf and 1,2-bis(2-aminoethoxy)ethane in the presence of Sm(NO3)3. The analyses of single-crystal structure reveal…
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Keywords:
selective colorimetric;
probe;
drug;
ion ... See more keywords
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Published in 2017 at "European journal of medicinal chemistry"
DOI: 10.1016/j.ejmech.2016.11.005
Abstract: A new mononuclear rhodium(III) complex, [Rh(bzimpy)Cl3] (bzimpy = 2,6-bis(2-benzimidazolyl)pyridine), was synthesized and characterized by elemental analysis and spectroscopic methods. The molecular structure of the complex was confirmed by single-crystal X-ray crystallography. The interaction of the complex with…
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Keywords:
dna;
spectroscopy;
iii complex;
rhodium iii ... See more keywords
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Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.07.040
Abstract: Abstract The synthesis, crystal structure and spectroscopic properties of the neodymium(III) complex [Nd(btpa)Cl 2 ]Cl·5H 2 O with btpa being the octadentate polypyridine ligand 6,6′-bis[bis(2-pyridylmethyl)aminomethyl]-2.2′-bipyridine are reported. The structure shows that the Nd 3+ ion…
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Keywords:
neodymium iii;
structure;
bis;
octadentate polypyridine ... See more keywords
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Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.10.063
Abstract: Abstract Novel luminescent tetranuclear Eu(III) complex [Eu(btfa)3(salbn)]4 (btfa: benzoyltrifluoroacetonate, salbn: N,N'-bis(salicylidene)-1,4-butanediamine) with characteristic cavity space is reported. The Eu(III) complex excited at 480 nm exhibits the highest photosensitized emission quantum yield (36%) reported for similar previously…
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Keywords:
iii;
luminescent tetranuclear;
tetranuclear iii;
cavity space ... See more keywords
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Published in 2019 at "International journal of biological macromolecules"
DOI: 10.1016/j.ijbiomac.2019.04.101
Abstract: A water-soluble polysaccharide was isolated from marine green algae Ulva pertusa and then chelated with iron to prepare the polysaccharide‑iron (III) complex. The immunomodulatory activities of sulfated polysaccharide and polysaccharide‑iron (III) complex were investigated through…
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Keywords:
iron;
iron iii;
iii complex;
polysaccharide iron ... See more keywords
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Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111311
Abstract: Gold(III) complex containing 2-pyridineethanol has been synthesized and characterized structurally by single crystal X-ray diffraction, vibrational spectroscopy, 1H NMR spectroscopy, electrochemical study, and DFT calculations. The Au(III) ion is four coordinated with one N-donor ligand…
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Keywords:
pyridineethanol;
gold iii;
spectroscopy;
iii complex ... See more keywords