Synthesis and Characterization of a New Neodymium Complex: DFT Insights and Potential Anticancer Applications
Sign Up to like & getrecommendations! Published in 2025 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.70067
Abstract: A new complex of type [Nd (HL) (NO3)2] has been synthesized with a Schiff base ligand H2L derived from 2‐hydroxy‐3‐methoxybenzaldehyde and L‐histidine. The structure of the synthesized complex was established using elemental analysis, molar conductivities,… read more here.
Keywords: iii; anticancer; dft; ligand ... See more keywords
A New Hetero‐Bimetallic [Fe(III)‐Mn(I)] Complex as a Dual Modality, Theranostic Tool for Photoactivated Anticancer Therapy
Sign Up to like & getrecommendations! Published in 2024 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.7881
Abstract: We developed a novel hetero‐bimetallic Fe(III)‐Mn(I) complex by combining hydroxyl radicals generating Fe(III)‐Phenolato/Carboxylato and CO‐releasing Mn(I)(CO)3 complexes to achieve a dual‐modality theranostic tool for photoactivated anticancer therapy. Fe(III)‐Phenolato/Carboxylato and Mn(I)(CO)3 complexes were conjugated through the… read more here.
Keywords: iii; bimetallic iii; hetero bimetallic; dual modality ... See more keywords
The Osteosarcoma Stem Cell Activity of a Gallium(III)‐Phenanthroline Complex Appended to Salicylate
Sign Up to like & getrecommendations! Published in 2022 at "Chembiochem"
DOI: 10.1002/cbic.202200532
Abstract: We report the synthesis, characterisation, and anti‐osteosarcoma properties of a gallium(III) complex (1) comprising of two 1,10‐phenanthroline ligands and salicylate, a non‐steroidal anti‐inflammatory drug. The gallium(III) complex 1 displays micromolar potency towards bulk osteosarcoma cells… read more here.
Keywords: iii complex; cell; osteosarcoma; gallium iii ... See more keywords
A Bioactive Benzimidazole-Cyclometalated Iridium(III) Complex as an Epigenetic Regulator through Effectively Interrupting the EED-EZH2 Interaction.
Sign Up to like & getrecommendations! Published in 2025 at "Small"
DOI: 10.1002/smll.202405771
Abstract: Epigenetic regulation plays a fundamental role in controlling gene expression and maintaining cellular identity. Among epigenetic processes, the translocation of methyltransferases is critical for the modification of chromatin structure and transcriptional activity. The regulation of… read more here.
Keywords: bioactive benzimidazole; iii complex; eed ezh2; interaction ... See more keywords
New cyclometalated gold (III) complex targeting thioredoxin reductase: exploring as cytotoxic agents and mechanistic insights
Sign Up to like & getrecommendations! Published in 2020 at "BioMetals"
DOI: 10.1007/s10534-020-00235-3
Abstract: A new cyclometalated Au(III) complex highlighting a naphthoquinone-C^N scaffold with formula (NQ-N^C)Au III (SAd)Cl, 1 , in which NQ-N^C: 2-(5-amino-benzo[h]quinolone)-3-(3-methyl-2-butenyl)-1,4-naphthoquinone, HSAd: 1-adamantanethiol, was synthesized and characterized. The interaction of complex 1 with cysteine (CysH) was… read more here.
Keywords: thioredoxin reductase; new cyclometalated; iii complex;
Lanthanum(III) complex as ferromagnetic supraprecursor for preparation of La2O3 nanoparticles by thermal decomposition method
Sign Up to like & getrecommendations! Published in 2019 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-019-03768-6
Abstract: A metal–organic framework lanthanum(III) complex with formula ([La(pydc)2(H2O)3]·4H2O)n (1), where pydc = pyridine-2,6-dicarboxylic acid, was synthesized through a sonochemical process. Complex 1 was characterized using elemental analysis, atomic absorption spectroscopy, conductivity measurements, Fourier-transform infrared (FT-IR) spectroscopy, thermogravimetric… read more here.
Keywords: la2o3 nanoparticles; lanthanum iii; spectroscopy; iii complex ... See more keywords
Trace Ir(III) complex enhanced electrochemiluminescence of AIE-active Pdots in aqueous media
Sign Up to like & getrecommendations! Published in 2020 at "Science China Chemistry"
DOI: 10.1007/s11426-019-9650-8
Abstract: Trace Ir(III) complex enhanced aggregation-induced electrochemiluminescence (AIECL) of poly-tetraphenylethene (pTPE) in aqueous media was investigated for the first time. The poly-TPE end-capped by Ir(III) complex (Ir@pTPE) and its corresponding model polymer poly-TPE (Ph@pTPE) could be… read more here.
Keywords: trace iii; iii; electrochemiluminescence; complex enhanced ... See more keywords
Phenoxazinone synthase and antimicrobial activity by a bis(1,3-diamino-2-propanolate) cobalt(III) complex
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1562-9
Abstract: In this work, we have synthesised and structurally characterized a mononuclear cobalt(III) complex, $$[\hbox {Co(2-O-pn)}_{2}]\hbox {Cl}^{.} \hbox {2H}_{2} \hbox {O}$$[Co(2-O-pn)2]Cl.2H2O (1), (2-O-pn = 1,3-diamino-2-propanolate). From the X-ray structure of the cobalt complex, it is revealed… read more here.
Keywords: cobalt iii; hbox hbox; cobalt; iii complex ... See more keywords
The selective colorimetric probe based on a macrocyclic Sm(III) complex for detecting lithium ion and its performance in the psychiatric drug
Sign Up to like & getrecommendations! Published in 2020 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2019.108027
Abstract: Abstract Herein a 23-membered macrocyclic mononuclear Sm(III) complex Sm-2f has been designed and synthesized via the Schiff-base cyclocondensation between extended dialdehyde H2Qf and 1,2-bis(2-aminoethoxy)ethane in the presence of Sm(NO3)3. The analyses of single-crystal structure reveal… read more here.
Keywords: selective colorimetric; probe; drug; ion ... See more keywords
Synthesis, structure, DNA/protein binding, and cytotoxic activity of a rhodium(III) complex with 2,6-bis(2-benzimidazolyl)pyridine.
Sign Up to like & getrecommendations! Published in 2017 at "European journal of medicinal chemistry"
DOI: 10.1016/j.ejmech.2016.11.005
Abstract: A new mononuclear rhodium(III) complex, [Rh(bzimpy)Cl3] (bzimpy = 2,6-bis(2-benzimidazolyl)pyridine), was synthesized and characterized by elemental analysis and spectroscopic methods. The molecular structure of the complex was confirmed by single-crystal X-ray crystallography. The interaction of the complex with… read more here.
Keywords: dna; spectroscopy; iii complex; rhodium iii ... See more keywords
Structure, stability and spectroscopic features of the neodymium(III) complex of the octadentate polypyridine ligand 6,6′-bis[bis(2-pyridylmethyl)aminomethyl]-2.2′-bipyridine
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.07.040
Abstract: Abstract The synthesis, crystal structure and spectroscopic properties of the neodymium(III) complex [Nd(btpa)Cl 2 ]Cl·5H 2 O with btpa being the octadentate polypyridine ligand 6,6′-bis[bis(2-pyridylmethyl)aminomethyl]-2.2′-bipyridine are reported. The structure shows that the Nd 3+ ion… read more here.
Keywords: neodymium iii; structure; bis; octadentate polypyridine ... See more keywords