Iron(III) 5,15-Diazaporphyrin Catalysts for the Direct Oxidation of C(sp3)-H Bonds.
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DOI: 10.1021/acs.inorgchem.0c02166
Abstract: 5,15-Diazaporphyrins are porphyrin analogues with imine-type sp2-hybridized nitrogen atoms at the meso-positions. Even though these compounds are more electron-deficient than regular porphyrins, the use of iron diazaporphyrins as catalysts has not been reported. Herein, we… read more here.
Keywords: iii diazaporphyrin; direct oxidation; iron iii;