Keggin-type polyoxometalate 1 : 1 complexes of Pb(II) and Bi(III): experimental, theoretical and luminescence studies.
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DOI: 10.1039/d1dt00499a
Abstract: Bi3+ and Pb2+ uptake by a monolacunary Keggin-type [PW11O39]7- anion leads to the formation of [PW11O39Bi]4- and [PW11O39Pb]5- complexes with a stereochemically active lone pair at the incorporated heterometal. The two complexes were isolated as… read more here.
Keywords: type polyoxometalate; keggin type; experimental theoretical; iii experimental ... See more keywords