The synthesis and characterization of an ortho-metallated iridium(III) hydride based on a pyridylpyrrole ligand
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114515
Abstract: Abstract Treatment of [Ir(PPh3)3Cl] with the 2-(1H-pyrrol-2-yl)pyridine (Hpp) ligand under refluxing toluene affords the iridium(III) hydride complex [Ir(H)Cl(pp)(PPh3)2] (1), whereas in the simultaneous presence of KOtBu the reaction gives iridium(III) hydride isomers, namely ortho-metallated triphenylphosphine… read more here.
Keywords: iii hydride; ligand; iridium iii; ortho metallated ... See more keywords
The DFT study on Rh–C bond dissociation enthalpies of (iminoacyl)rhodium(III)hydride and (iminoacyl)rhodium(III)alkyl
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.12.042
Abstract: Abstract Rhodium transition-metal-organic cooperative catalysis, which has been intensively studied by many chemists, represents a great success in C–H bond activation because of high efficiencies and selectivities. Typically, in the reaction mechanism of aldehyde and… read more here.
Keywords: rhodium iii; iminoacyl rhodium; bond; iii hydride ... See more keywords
Control over Selectivity in Alkene Hydrosilylation Catalyzed by Cobalt(III) Hydride Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02094
Abstract: Two new bisphosphine [PCP] pincer cobalt(III) hydrides, [(L1)Co(PMe3)(H)(Cl)] (L11, L1 = 2,6-((Ph2P)(Et)N)2C6H3) and [(L2)Co(PMe3)(H)(Cl)] (L21, L2 = 2,6-((iPr2P)(Et)N)2C6H3), as well as one new bissilylene [SiCSi] pincer cobalt(III) hydride, [(L3)Co(PMe3)(H)(Cl)] (L31, L3 = 1,3-((PhC(tBuN)2Si)(Et)N)2C6H3), were synthesized… read more here.
Keywords: iii hydride; cobalt; cobalt iii; alkene hydrosilylation ... See more keywords