Mn(III)-Iodosylarene Porphyrins as an Active Oxidant in Oxidation Reactions: Synthesis, Characterization, and Reactivity Studies.
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DOI: 10.1021/acs.inorgchem.8b01426
Abstract: Mn(III)-iodosylarene porphyrin adducts, [Mn(III)(ArIO)(Porp)]+, were synthesized by reacting electron-deficient Mn(III) porphyrin complexes with iodosylarene (ArIO) at -60 °C and characterized using various spectroscopic methods. The [Mn(III)(ArIO)(Porp)]+ species were then investigated in the epoxidation of olefins… read more here.
Keywords: porphyrin; iii iodosylarene; oxidation; active oxidant ... See more keywords
Mutable Properties of Nonheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism.
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DOI: 10.1021/jacs.7b03310
Abstract: Although nonheme iron(III)-iodosylarene complexes present amazing oxidative efficiency and selectivity, the nature of such complexes and related oxidation mechanism are still unsolved after decades of experimental efforts. Density functional calculations were employed to explore the… read more here.
Keywords: mechanism; iii iodosylarene; iron; iron iii ... See more keywords