A ligand-based conjugate solid sensor for colorimetric ultra-trace gold(III) detection in urban mining waste
Sign Up to like & getrecommendations! Published in 2019 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2019.123842
Abstract: Abstract Detection of trace level gold (Au(III)) ion with rapid and cheaper colorimetric detections was performed. Herein, the organic ligand of 4-aminoantipyrine (AAP) was facilely supported onto the mesoporous silica nanospheres as a scaffold. The… read more here.
Keywords: trace; solid sensor; iii ion; detection ... See more keywords
Enhancing Luminescence in Lanthanide Coordination Polymers Through Dilution of Emissive Centers
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2018.01.045
Abstract: Abstract A Ln-adipate metal-organic framework templated with 4,4′-bipyridine (GWMOF-6) was synthesized with Eu(III) or Tb(III) ions with various concentrations of optically inert Gd(III) ion in order to evaluate the effects of diluting the emissive metal… read more here.
Keywords: luminescence lanthanide; iii ion; coordination polymers; luminescence ... See more keywords
The efficient sensitization of Sm(III) ion by a macrocycle with the matched cavity and energy level
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114133
Abstract: Abstract A series of mononuclear lanthanide(III) coordination compounds Ln-1a with the “lasso-type” protection have been synthesized based on the flexible [1+1] pendant-arm Schiff-base macrocyclic ligand H2L1a. X-ray structure analysis reveals that the central ten-coordinate Ln(III)… read more here.
Keywords: macrocyclic ligand; energy; iii ion; cavity ... See more keywords
Characterization of a Mixed-Valence Ru(II)/Ru(III) Ion-Pair Complex. Unexpected High-Frequency Electron Paramagnetic Resonance Evidence for Ru(III)-Ru(III) Dimer Coupling.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01068
Abstract: In this contribution, we report the synthesis and full characterization of the first mixed-valence Ru(II)/Ru(III) ion-pair complex, [RuII(bipy)2(pic)]+[cis-RuIIICl2(pic)2]-, in the solid state and in aqueous solution, where bipy = 2,2'-bipyridine and pic- = picolinate. In… read more here.
Keywords: valence iii; pair complex; iii ion; mixed valence ... See more keywords
Clinically used antifungal azoles as ligands for gold(III) complexes: the influence of the Au(III) ion on the antimicrobial activity of the complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00411a
Abstract: In a search for novel antimicrobial metal-based therapeutic agents, mononuclear gold(III) complexes 1-7 of the general formula [AuCl3(azole)], where azole stands for imidazole (im, 1), 1-isopropylimidazole (ipim, 2), 1-phenylimidazole (phim, 3), clotrimazole (ctz, 4), econazole… read more here.
Keywords: iii complexes; iii; iii ion; clinically used ... See more keywords