A novel manganese(III)-peroxo complex bearing a proline-derived pentadentate aminobenzimidazole ligand
Sign Up to like & getrecommendations! Published in 2018 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2018.04.036
Abstract: Abstract Manganese(III)-peroxo complexes are invoked as key intermediates in the enzymatic cycles of Mn-containing enzymes, and the synthesis of reactive manganese(III)-peroxo complexes with rationally designed ligand has been of great interest in the communities of… read more here.
Keywords: manganese iii; pentadentate aminobenzimidazole; aminobenzimidazole ligand; peroxo complex ... See more keywords
Hydrogen Bonding Effect on the Oxygen Binding and Activation in Cobalt(III)-Peroxo Complexes
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c04260
Abstract: Cobalt(III)peroxo complexes serve as model metal complexes mediating oxygen activation. We report a systematic study of the effect of hydrogen bonding on the O2 binding energy and the O–O bond activation within the cobalt(III)peroxo complexes.… read more here.
Keywords: hydrogen bonding; cobalt iii; peroxo; iii peroxo ... See more keywords
Keto-Enol Tautomerization Triggers an Electrophilic Aldehyde Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b10033
Abstract: Oxygen atom transfer by high-valent enzymatic intermediates remains an enigma in chemical catalysis. In particular, manganese is an important first-row metal involved in key biochemical processes, including the biosynthesis of molecular oxygen (through the photosystem… read more here.
Keywords: manganese iii; mechanism; aldehyde deformylation; reaction ... See more keywords