A titanium(III) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer.
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DOI: 10.1039/d1cc01190a
Abstract: A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle… read more here.
Keywords: iii phosphite; electron transfer; proton; titanium iii ... See more keywords