Synthesis of Phosphinic Amides from Chlorophosphines and Hydroxyl Amines via P(III) to P(V) Rearrangement.
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DOI: 10.1021/acs.orglett.3c00229
Abstract: Phosphoranyl radicals are essential mediators to bring about new radicals but often produce a stoichiometric amount of phosphine oxide/sulfide waste. Herein, we devised a phosphorus-containing species as a radical precursor, but without the generation of… read more here.
Keywords: iii rearrangement; via iii; amides chlorophosphines; synthesis phosphinic ... See more keywords