Synthesis, characterization and catechol oxidase mimicking activity of two iron(III) schiff base complexes
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DOI: 10.1016/j.poly.2017.12.037
Abstract: Abstract Two new mononuclear iron(III) Schiff base complexes [Fe(L1)2]SCN (1) and [Fe(L2)(HL3)]ClO4 (2) {where HL1 = 1-((3-amino-2,2-dimethylpropylimino)methyl)naphthalen-2-ol, H2L2 = N,N′-bis(3-ethoxysalicylidene)2,2-dimethyl-1,3-propanediamine and HL3 = 2-((3-amino-2,2-dimethylpropylimino)methyl)-6-ethoxyphenol} have been synthesized and characterized by elemental and several spectral analyses. Single crystal X-ray structure determination confirmed… read more here.
Keywords: iii schiff; catechol oxidase; oxidase mimicking; base complexes ... See more keywords
A manganese(iii) Schiff base complex immobilized on silica-coated magnetic nanoparticles showing enhanced electrochemical catalytic performance toward sulfide and alkene oxidation
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DOI: 10.1039/d0ra02728f
Abstract: In this study, a novel Mn(III)–Schiff base complex was synthesized and characterized. The structure of this complex was determined to be a deformed octahedral coordination sphere by single-crystal X-ray diffraction analysis. The Mn(III)–Schiff base complex… read more here.
Keywords: iii schiff; oxidation; microscopy; base complex ... See more keywords
Synthesis, Characterization, and Catalytic Studies of Mn(III)-Schiff Base-Dicyanamide Complexes: Checking the Rhombicity Effect in Peroxidase Studies
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DOI: 10.1155/2017/5465890
Abstract: The condensation of 3-methoxy-2-hydroxybenzaldehyde and the diamines 1,2-diphenylendiamine, 1,2-diamine-2-methylpropane and 1,3-propanediamine yielded the dianionic tetradentate Schiff base ligands N,N′-bis(2-hydroxy-4-methoxybenzylidene)-1,2-diphenylendiimine (H2L1), N,N′-bis(2-hydroxy-4-methoxybenzylidene)-1,2-diamino-2-methylpropane (H2L2) and N,N′-bis(2-hydroxy-4-methoxybenzylidene)-1,3-diaminopropane (H2L3) respectively. The organic compounds H2L1 and H2L2 have been characterized… read more here.
Keywords: iii schiff; peroxidase; rhombicity; base ... See more keywords