Structure and reactivity of the first-row d-block metal-superoxo complexes.
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DOI: 10.1039/c9dt01402k
Abstract: In the first-row of d-block metals, ten elements are included, such as scandium (Sc, 3d1), titanium (Ti, 3d2), vanadium (V, 3d3), chromium (Cr, 3d54s1), manganese (Mn, 3d5), iron (Fe, 3d6), cobalt (Co, 3d7), nickel (Ni,… read more here.
Keywords: superoxo; superoxo complexes; iii superoxo; first row ... See more keywords
Ambiphilicity of a mononuclear cobalt(III) superoxo complex.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc05337f
Abstract: Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged… read more here.
Keywords: iii superoxo; coiii; ambiphilicity mononuclear; superoxo complex ... See more keywords