Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.8b00549
Abstract: The redox interconversion between Co(III) thiolate and Co(II) disulfide compounds has been investigated experimentally and computationally. Reactions of cobalt(II) salts with disulfide ligand L1SSL1 (L1SSL1 = di-2-(bis(2-pyridylmethyl)amino)-ethyl disulfide) result in the formation of either the… read more here.
Keywords: iii thiolate; cobalt; redox interconversion; compound ... See more keywords
Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(III)-thiolate from Co(II)-disulfide complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02106d
Abstract: The formation of Co(III)-thiolate complexes from Co(II)-disulfide complexes using the anionic ligand 8-quinolinolate (quin-) has been studied experimentally and quantum chemically. Two Co(II)-disulfide complexes [Co2(LxSSLx)(Cl)4] (x = 1 or 2; L1SSL1 = 2,2'-disulfanediylbis(N,N-bis(pyridin-2-ylmethyl)ethan-1-amine; L2SSL2 =… read more here.
Keywords: disulfide complexes; thiolate; quin; iii thiolate ... See more keywords