Synthesis of Four Illudalane Sesquiterpenes Utilizing a One-Pot Diels-Alder/Oxidative Aromatization Sequence.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02511
Abstract: The concise, divergent total syntheses of four illudalane sesquiterpenes using an indanone as the key intermediate are reported. The key elements in these total syntheses, which involve only four to six operational steps, consist of… read more here.
Keywords: diels alder; four illudalane; illudalane sesquiterpenes; alder oxidative ... See more keywords
Divergent total syntheses of five illudalane sesquiterpenes and assignment of the absolute configuration.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc00933g
Abstract: Concise, divergent total syntheses of five bioactive illudalane sesquiterpenes have been achieved. Our synthesis features an intermolecular [2+2+2] cycloaddition, and a lactone-directed aromatic C-H oxygenation to generate a temporary phenolic hydroxyl group which enables regioselective… read more here.
Keywords: total syntheses; syntheses five; divergent total; illudalane sesquiterpenes ... See more keywords