Molecular Capacitors: Accessible 6- and 8-Electron Redox Chemistry from Dimeric "Ti(I)" and "Ti(0)" Synthons Supported by Imidazolin-2-Iminato Ligands.
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DOI: 10.1021/acs.inorgchem.2c02881
Abstract: Reduction of the diamagnetic Ti(III)/Ti(III) dimer [Cl2Ti(μ-NImDipp)]2 (1) (NImDipp = [1,3-bis(Dipp)imidazolin-2-iminato]-, Dipp = C6H3-2,6-iPr2) with 4 and 6 equiv of KC8 generates the intramolecularly arene-masked, dinuclear titanium compounds [(μ-N-η6-ImDipp)Ti]2 (2) and {[(Et2O)2K](μ-N-μ-η6:η6-ImDipp)Ti}2 (3), respectively, in… read more here.
Keywords: cot; imdippn; chemistry; imidazolin iminato ... See more keywords