NHC-induced conversion of a W–Ge double bond into the triple bond through formation of W–Ge single and double bonded intermediates
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DOI: 10.1016/j.jorganchem.2017.07.027
Abstract: Abstract Reaction of hydrido(hydrogermylene) complex Cp*(CO) 2 (H)W=Ge(H)(Tsi) ( 1 , Tsi = C(SiMe 3 ) 3 ) with 1 equiv of Me IMe ( Me IMe = 1,3-dimethyl-4,5-dimethylimidazol-2-ylidene) immediately afforded NHC-stabilized germylene complex Cp*(CO) 2 (H)WGe(H)( Me IMe)(Tsi)… read more here.
Keywords: ime; tsi; bond; complex tsi ... See more keywords